Holy thread resurrection Batman
In one of those "I must get round to checking that" moments I decided to see just what damage my Tubolito had suffered and what potential repairs might resurrect it. After all it weren't cheap and for one use it would have turned out bloomin' expensive
A test inflate and it's not even holding air for a second. The reason why is obvious - there's a ruddy hole in it! I didn't have any McNett repair/tenacious tape but I did have some Topeak self-adhesive patches. Would they work? Yes they do!
Antiseptic wipe the tube to clean it, roughen up with sandpaper, on with patch and press for a minute. And inflate. Except there's a hissing sound
Seven pin-prick holes and patches later the tube stays inflated

I used both Topeak and Park GP-2 patches, both seem to work OK. Only problem is that the tube is now 3g heavier due to all the patches! Actually not quite true, the larger hole might need a larger patch of McNett tape as the edges of the hole haven't bonded to the patch - the patches are clear so you can see the tube through them.
So obviously my tyre had more thorns in that I'd been able to locate by running my fingers around the inside (several times). Because I'd been tubeless the sealant had done its job without me noticing. The thorns will have been "inside" the carcase and only pressed out so that they damaged the tube when that part of the tyre was pushed against a stone or edge retracting back so they couldn't be found. I don't think that's a problem with the Tubolito per se but with all tubes being added to a tubeless tyre.
The lesson seems to be that if you run tubeless you really need to commit to it as hidden or embedded thorns and sharps will damage any tube so they really are "emergency only" use.